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Química Bachillerato

What factors affect the rate of a chemical reaction?

Escrito y revisado por profesores de Studoli · Actualizado

Respuesta corta

The rate of reaction increases with higher temperature, higher concentration (or pressure for gases), larger surface area and the presence of a catalyst. Collision theory explains why: particles react only when they collide with enough energy (the activation energy), and each factor increases the frequency or energy of collisions.

Paso a paso

  1. Temperature: particles move faster, collide more often and more collisions have enough energy.
  2. Concentration or pressure: more particles in the same space, so more frequent collisions.
  3. Surface area: smaller pieces or powder expose more particles to collisions.
  4. Catalyst: provides a different pathway with a lower activation energy and is not used up.

Ejemplo resuelto

Marble chips and hydrochloric acid

  • Powdered marble reacts faster than large chips
  • Warmer acid reacts faster than cold acid
  • Measure the rate by recording the volume of CO₂ given off each minute

Errores comunes

  • Saying particles collide harder at higher concentration. They collide more often, not harder.
  • Saying a catalyst gives particles more energy. It lowers the activation energy instead.
  • Leaving out the word frequency when explaining collision theory.

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